And West Ham’s 4-1 win over Huddersfield is the first game of the show.
The Hammers are then followed by their London rivals Tottenham, who thrashed Everton at Wembley.
Key victories for West Brom and Crystal Palace follow before a controversial end at Vicarage Road between Watford and Southampton.
Newcastle vs Swansea is the penultimate game then Chelsea closes out the programme with their match against Leicester.
Lineker wrote on Twitter: “MOTD running order: Hud/WHU, Tot/Eve, WBA/Bri, CP/Bur, Wat/Sou, New/Swa, Che/Lei. Lots of good stuff.”
Lineker will be joined on the sofa by Ian Wright and Frank Lampard from 10.30pm.
Full running order below…
Huddersfield vs West Ham,
Tottenham vs Everton
West Brom vs Brighton
Crystal Palace vs Burnley
Watford vs Southampton
Newcastle vs Swansea
Chelsea vs Leicester